Yes, a V-8 can go in an AWD (there are examples here on the site) BUT not as easily as in a RWD. The oil pan needs to be modified for the front axle, and I think the motor mounts are different than the RWD version, plus the AWD ones are currently unavailable (IIRC). See if some of the V-8 AWD crew will sound off...
-Andrew
-Andrew