I'll start off with my smog results from a few weeks ago:

-Check engine light was an easy fix, replace the bulb in the cluster, and no problem.
-The P0446 is likely the purge valve. That's been replaced, and I'm just waiting on the readiness monitor for EVAP to clear. No code has come back yet.
-The P0420 Cat Efficiency Below Threshold, and the associated high emissions test is what I need help with.
The first thing I did was get something so that I can see what the fuel trim values were, to see if there were any crazy vacuum leaks or what not. Conveniently the wifi OBD2 reader I bought also shows me codes and readiness monitors and allows me to to reset, which was also needed in my quests to pass smog.
At idle:

At 2500 rpm:

Everything looked pretty normal, and the oxygen sensor voltages were bouncing back and forth like they should, but the thing that stood out was that Long Term fuel trim was double digit negative values at idle, and these would lessen at high loads. According to what I read online:
Running too rich – High negative fuel trim corrections can be caused by MAF sensor problems, high fuel pressure, leaking fuel pressure regulator diaphragm, faulty evaporative emissions components, leaking injectors, defective O2 sensors, exhaust leaks/pinholes before the O2 sensor, coolant temp sensor problems, and base engine issues such as low compression and incorrect camshaft timing.
The leaky injector part stood out since the issue was worse at idle, where the small amount of leaking fuel would make the biggest difference. To deal with this, I did the central sequential fuel injection to multiport sequential fuel injection conversion, and this also included a new fuel pressure regulator, and I got to replace a few gaskets that might be leaking as well.
After dealing with a throttle position sensor and idle control valve that started acting up after the conversion, the van runs great; better than before. It's smoother and quieter than it was before, and fuel trims are significantly better looking now. Long term fuel trim is -3.7% at idle, +3.1 under low to moderate throttle, and +7% under heavy throttle. Not perfect, but nothing terrible and much closer to what everything should be. Mostly within the realm of what minor vacuum leaks would cause.
Everything was looking good, mot of the readiness monitors were about to complete, and the P0420 came back...
I'm really thinking it's a catalytic converter at this point, so I started taking out the catalytic converter section today, and I got nothing but frustration. It looked like it's been replaced before, since there were two difference sizes of nuts holding the section to the manifolds and exhaust, and an odd weld int he middle of one pipe. One of the the nuts attaching it to the rear section was so badly seized that I twisted the stud into two pieces during removal, great. So after struggling to get the catalytic converter section out, I then proceed to remove the oxygen sensors; two out of four tear out the threads on their way out, excellent!
Now here is the part that really did it for me, the catalyst material inside looks brand new, and I can't tell if the oxygen sensors are normal, or if they are fouled. They all have a whitish coating, which seems like the pictures I've seen of either coolant or silicone contamination. They all have white on them, aside from the pre-cat sensor, which just has minimal amounts.


So... Any ideas?